Bis(η5-pentamethylcyclopentadienyl)cobalt(II)
نویسندگان
چکیده
The crystal structure of the title compound, deca-methyl-cobaltocene, [Co(C(10)H(15))(2)], has been determined. High-quality single crystals were grown from a cold saturated hexa-methyl-disiloxane solution. The structure is related to the manganese and iron analogs. The molecule has D(5d) symmetry, with the Co atom in a crystallographic 2/m position. The cobalt-centroid(C(5)) distance is 1.71Å and the centroid(C(5))-Co-centroid(C(5)) angle is 180°, by symmetry.
منابع مشابه
[1,2-Bis(diphenylphosphino)ethane]chlorido(η5-pentamethylcyclopentadienyl)iron(II) dichloromethane solvate
In the title compound, [Fe(C(10)H(15))Cl(C(26)H(24)P(2))]·CH(2)Cl(2), the Fe(II) atom is coordinated by two P atoms from a 1,2-bis-(diphenyl-phosphino)ethane ligand [Fe-P = 2.2130 (7) and 2.2231 (7) Å], a chloride anion [Fe-Cl = 2.3329 (7) Å] and a penta-methyl-cyclo-penta-dienyl (Cp*) ligand [Fe-centroid(Cp*) = 1.732 (3) Å] in a typical piano-stool geometry. In the crystal structure, the compl...
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The acknowledgement in the paper by Munie, Larsen & Gembicky [Acta Cryst. (2008), E64, m293] is extended and an omitted reference is added.[This corrects the article DOI: 10.1107/S1600536807067426.].
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